this post was submitted on 05 Dec 2023
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I'm not sure I understand the confusion. The material thickness does matter in that thinner materials will resist current flow due to a lack of charge carriers meaning each must travel faster, which means that more charge separation is required for a given recombination rate or current.
If the charge required is too high (more than the potential difference across the depletion zone) then the build up will prevent charge separation after excitation. They will recombine in the depletion zone making a bunch of heat and burning out the cell.
Maybe that's the thing? super thin films under too much irradiation or load cooking themselves due to inability to move excited charges away fast enough?